Pick flowers that are open but not going to seed. Hang them in bunches, upside down. Once they're dry, put them in paper bags until you're ready to use them.
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We got an amazing range of colors with goldenrod. Post-mordanting with iron really changed the color from gold to deep olive greens.
Goldenrod takes much better on protein fibers than cellulose fibers. Look at the top [left] card in the pic, right. That's cotton. Not much color took at all.
To dye with goldenrod, cut the stems and leaves off and let the flowering parts [fresh or dry] soak in warm water overnight. The next day, boil for an hour, then strain the plant parts out and put your fiber in.
Tip: Use quilt batt inside a large funnel to strain the plant material out. The polyester batts rinse clean and can be used during you next dye day.